Add a user to a SharePoint group using PowerShell
It’s fairly easy to add a user to a SharePoint group using the New-SPUser command. All you need to know is the URL of the site, the name of the user and the group they are to become a member of. I used the command below to add a domain user account to the WebbWorld Portal Owners group:
New-SPUser -UserAlias “WebbWorld\Dave.Webb” -Web “http://intranet” -Group WebbWorld Portal Owners”